A new analytical approach based on asymmetrical flow field-flow fractionation coupled to ultraviolet spectrometry and light scattering detection for SWCNT aqueous dispersion studies

Julien Gigault , Bruno Grassl (1) , Gaetane Lespes (1)

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

This work demonstrates the potential of asymmetrical flow field-flow fractionation (A4F) coupled to Ultraviolet spectrometry (UV) and multi-angle light scattering (MALS) for the study of single-walled carbon nanotube (SWCNT) dispersion in aqueous solutions containing a surfactant. The results indicate that this technique is a powerful analytical tool that is able to evaluate SWCNT dispersion states in aqueous media and, more importantly, determine the presence or absence of aggregates, the numbers and sizes of different SWCNT populations and the SWCNT size distribution. Dynamic light scattering was employed to complete and demonstrate the relevance of the data that were obtained via A4F-UV-MALS. Two different anionic surfactants that are used to disperse SWCNTs were then studied. The dispersing powers of the surfactants were experimentally evaluated based on their structural organizations. This study demonstrates that surfactant concentration and sonication energy are key parameters that control the SWCNT dispersion state and SWCNT structural integrity therein. © The Royal Society of Chemistry 2012.

Keywords: carbon nanotube; surfactant; article; chemistry; field flow fractionation; instrumentation; methodology; radiation scattering; solution and solubility; ultraviolet spectrophotometry; Fractionation; Field Flow; Light; Nanotubes; Carbon; Particle Size; Scattering; Radiation; Solutions; Spectrophotometry; Ultraviolet; Surface-Active Agents; Water

Domains: Chemical Sciences

Julien Gigault, Bruno Grassl, Gaetane Lespes. A new analytical approach based on asymmetrical flow field-flow fractionation coupled to ultraviolet spectrometry and light scattering detection for SWCNT aqueous dispersion studies. Analyst, 2012, 137 (4), pp.917-923. ⟨10.1039/c2an15449h⟩. ⟨hal-01598466⟩