Heterogeneous sulfoxidation of thioethers by hydrogen peroxide over layered double hydroxides as catalysts

Claude Guimon (1, 2) , A. Cordoneanu , S. Casenave , T. Hulea , C. Chelaru , Hervé Martinez (2) , V. Hulea (3) , E. Dumitriu (4)

1 LCTPCM - Laboratoire de Chimie théorique et Physico-chimie moléculaire
2 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux
3 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
4 Tecnical University of Iasi

A new method for mild oxidation of thioethers with hydrogen peroxide in heterogeneous catalysis is described. The layered double hydroxides (or hydrotalcite-like materials) act as basic catalysts for the sulfoxidation reaction with hydrogen peroxide in the presence of acetonitrile. The influence of the nature of thioether, the type of catalyst, the reaction temperature and reaction time on the catalytic activity and selectivity in this reaction has been investigated. A mechanism of the sulfoxidation reaction is proposed. © 2001 Elsevier Science B.V.

Keywords: acetonitrile; Catalyst activity; Catalytic activity; Ethers; Hydrogen peroxide; Sulfonation; Sulfoxidation; Sulfoxidation reaction; Thioether; Thioethers

Domains: Chemical Sciences; Material chemistry

Claude Guimon, A. Cordoneanu, S. Casenave, T. Hulea, C. Chelaru, et al.. Heterogeneous sulfoxidation of thioethers by hydrogen peroxide over layered double hydroxides as catalysts. Catalysis Today, 2001, 66 (2-4), pp.529--534. ⟨10.1016/S0920-5861(00)00627-1⟩. ⟨hal-01503988⟩