Electronic structure of stable radicals of the heavy group 14 elements: UV-photoelectron spectroscopy characterization
Résumé
A series of stable persilyl-substituted heavy group 14 element-centered radicals (tBu2MeSi)3E* (E = Si, Ge, Sn) was studied by UV-photoelectron spectroscopy in order to determine the values of the first ionization energies of the title species and to make a systematic comparison of their ease of oxidation.