Electronic structure of stable radicals of the heavy group 14 elements: UV-photoelectron spectroscopy characterization

Anna Chrostowska (1) , Alain Dargelos (1) , Alain Graciaa (2) , Patrick Baylère (1) , V.Y. Lee (3) , A. Sekiquchi (3)

1 IPREM - Institut pluridisciplinaire de recherche sur l'environnement et les matériaux
2 TEFC - Thermodynamique et Energétique des fluides complexes
3 Department of chemistry- Graduate school of pure an applied sciences

A series of stable persilyl-substituted heavy group 14 element-centered radicals (tBu2MeSi)3E* (E = Si, Ge, Sn) was studied by UV-photoelectron spectroscopy in order to determine the values of the first ionization energies of the title species and to make a systematic comparison of their ease of oxidation.

Domaines: Chimie-Physique [physics.chem-ph]

Anna Chrostowska, Alain Dargelos, Alain Graciaa, Patrick Baylère, V.Y. Lee, et al.. Electronic structure of stable radicals of the heavy group 14 elements: UV-photoelectron spectroscopy characterization. Organometallics, 2008, 27 (13), pp.2915-2917. ⟨10.1021/om7012925⟩. ⟨hal-00340037⟩