Silver-mediated intramolecular P–C coupling

György Szalóki (1) , Karinne Miqueu (2) , D. Bourissou (1)

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée
2 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

Silver(I) salts mimic copper(I) but not gold(I) salts in the reaction with peri-iodo naphthyldiisopropylphosphine. The formation of the corresponding peri-cyclic phosphonium derivatives represents the first example of silver-mediated P–C coupling through a two-electron redox sequence.

Domains: Material chemistry; Polymers; Theoretical and/or physical chemistry; Analytical chemistry

György Szalóki, Karinne Miqueu, D. Bourissou. Silver-mediated intramolecular P–C coupling. Mendeleev Communications, 2022, 32 (1), pp.78-79. ⟨10.1016/j.mencom.2022.01.025⟩. ⟨hal-03607552⟩