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Silver-mediated intramolecular P–C coupling

Abstract : Silver(I) salts mimic copper(I) but not gold(I) salts in the reaction with peri-iodo naphthyldiisopropylphosphine. The formation of the corresponding peri-cyclic phosphonium derivatives represents the first example of silver-mediated P–C coupling through a two-electron redox sequence.
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Submitted on : Monday, March 14, 2022 - 9:26:07 AM
Last modification on : Monday, July 4, 2022 - 9:25:54 AM

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György Szalóki, Karinne Miqueu, D. Bourissou. Silver-mediated intramolecular P–C coupling. Mendeleev Communications, Elsevier, 2022, 32 (1), pp.78-79. ⟨10.1016/j.mencom.2022.01.025⟩. ⟨hal-03607552⟩

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