 |
 |
Journal articles
Germylene-β-sulfoxide Hemilabile Ligand in Coordination Chemistry
Abstract : We describe herein the synthesis of a germylene-β-sulfoxide ligand, 1, and its abilities in coordination chemistry. Treatment of 1 with metal complexes [W(cod)(CO)4], [Mo(nbd)(CO)4] and [Ni(cod)2] afforded the corresponding (1)-chelated metal complexes (1)-W(CO)4 (2a), (1)-Mo(CO)4 (2b), and (1)-Ni(cod) (4a), clearly showing a bidentate ligation of the metal by the germanium(II) and sulfur centers. Coordination with [Ru(PPh3)3Cl2] afforded an unprecedented bridged bis-(ruthenium) complex 3b. In the case of 4a, the hemilability of the bidentate ligand 1 was demonstrated by sulfoxide substitution by a CO ligand.
https://hal-univ-pau.archives-ouvertes.fr/hal-03113350
Contributor : Sylvie Blanc Connect in order to contact the contributor
Submitted on : Friday, January 14, 2022 - 3:25:31 PM
Last modification on : Monday, July 4, 2022 - 9:45:28 AM
Long-term archiving on: : Friday, April 15, 2022 - 6:13:18 PM
Contributor : Sylvie Blanc Connect in order to contact the contributor
Submitted on : Friday, January 14, 2022 - 3:25:31 PM
Last modification on : Monday, July 4, 2022 - 9:45:28 AM
Long-term archiving on: : Friday, April 15, 2022 - 6:13:18 PM
File
Inorg Chem manuscript-revised-...
Files produced by the author(s)