Co3O4 Nanoparticles Embedded in Mesoporous Carbon for Supercapacitor Applications
Résumé
Metal oxides are of great interest for supercapacitor application; however, they suffer from capacity fading during cycling and limited cycle life. In this work, a one-pot bottom-up approach is proposed to design cobalt oxide (Co 3 O 4) nanoparticles confined in a mesoporous carbon. This involved the coassembly of a phenolic resin, a surfactant, and a cobalt salt followed by a high temperature pyrolysis (600−800°C) and a subsequent low temperature oxidation (190−240°C) step. Very small Co 3 O 4 particle size (2.3−7.4 nm) could be achieved for high loadings of Co 3 O 4 (up to 59%) in the carbon network. Both the pyrolysis and oxidation temperature increase led to an increase of nanoparticle size, porosity and electronic conductivity. At low temperatures, i.e., 600 and 650°C , and despite the low particle size, the performances are poor and limited by the carbon low electronic conductivity. At high temperature (800°C), the conductivity is improved translating in a higher capacitance, but the larger and more aggregated nanoparticles induced low rate capability. The best compromise to maintain high capacitance and rate capability was observed at 700 and 750°C and thus for composite materials combining simultaneously dispersed nanoparticles, high porosity, and good electronic conductivity. In particular, the material treated at 750°C presents, in a 2 electrode system using 2 M KOH, a capacitance of 54 F g −1 at 0.1 A g −1 , a very high rate capability of 48.7% at 10 A g −1 , and a superior rate performance of 82% after 10000 cycles.
Domaines
Matériaux
Fichier principal
Zallouz et al. App. Nano Materials, 2021-HAL.pdf (1.84 Mo)
Télécharger le fichier
Supporting Information- Zallouz et al. App. NAno. Mater., 2021 - HAL .pdf (1.46 Mo)
Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)