Germylene-β-sulfoxide Hemilabile Ligand in Coordination Chemistry - Archive ouverte HAL Access content directly
Journal Articles Inorganic Chemistry Year : 2021

Germylene-β-sulfoxide Hemilabile Ligand in Coordination Chemistry

(1) , (1) , (2) , (3) , (1) , (1) , (1)
1
2
3

Abstract

We describe herein the synthesis of a germylene-β-sulfoxide ligand, 1, and its abilities in coordination chemistry. Treatment of 1 with metal complexes [W(cod)(CO)4], [Mo(nbd)(CO)4] and [Ni(cod)2] afforded the corresponding (1)-chelated metal complexes (1)-W(CO)4 (2a), (1)-Mo(CO)4 (2b), and (1)-Ni(cod) (4a), clearly showing a bidentate ligation of the metal by the germanium(II) and sulfur centers. Coordination with [Ru(PPh3)3Cl2] afforded an unprecedented bridged bis-(ruthenium) complex 3b. In the case of 4a, the hemilability of the bidentate ligand 1 was demonstrated by sulfoxide substitution by a CO ligand.
Fichier principal
Vignette du fichier
Inorg Chem manuscript-revised-08122020.pdf (704.42 Ko) Télécharger le fichier
Origin : Files produced by the author(s)

Dates and versions

hal-03113350 , version 1 (14-01-2022)

Identifiers

Cite

Nicolas Lentz, Cynthia Cuevas-Chávez, Sonia Mallet-Ladeira, Jean-Marc Sotiropoulos, Antoine Baceiredo, et al.. Germylene-β-sulfoxide Hemilabile Ligand in Coordination Chemistry. Inorganic Chemistry, 2021, 60 (1), pp.423-430. ⟨10.1021/acs.inorgchem.0c03101⟩. ⟨hal-03113350⟩
75 View
94 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More