Gold@Prussian blue analogue core–shell nanoheterostructures: their optical and magnetic properties

Guillaume Maurin-Pasturel , Ekaterina Mamontova , Maria A Palacios , Jérôme Long , Joachim Allouche (1) , Jean-Charles Dupin , Yannick Guari , Joulia Larionova

1 IPREM - Institut pluridisciplinaire de recherche sur l'environnement et les matériaux

Analogues (PBA) shell nanoheterostructures are multifunctional nano-objects combining optical properties (Surface Plasmon Resonance) of the Au core and magnetic properties of the PBA shell. We report in this article a series of new Au core@PBA shell nano-objects with different PBA shells: Au@K/Co/[Fe II (CN)6] (2) and Au@K/Ni/[Cr III (CN)6]:[Fe II (CN)6] (3) single PBA shell, as well as Au@K/Ni/[Fe II (CN)6]@K/Ni/[Fe III (CN)6] (4) double PBA shell and Au@K/Ni/[Fe II (CN)6]@K/Ni/[Fe III (CN)6]@K/Ni/[Cr III (CN)6] (5) triple PBA shell systems. The position and intensity of the Au SPR band, as well as the magnetic behaviour of the nanoheterostructures are strongly affected by the shell composition and its thickness.

Domains: Chemical Sciences; Material chemistry; Chemical Sciences; Inorganic chemistry; Chemical Sciences; Other

Guillaume Maurin-Pasturel, Ekaterina Mamontova, Maria A Palacios, Jérôme Long, Joachim Allouche, et al.. Gold@Prussian blue analogue core–shell nanoheterostructures: their optical and magnetic properties. Dalton Transactions, 2019, 48 (18), pp.6205-6216. ⟨10.1039/C9DT00141G⟩. ⟨hal-03054377⟩