E. Jakobs, Telefon, Email oder Fax?, Schreiben fürs Netz, vol.Fax, pp.26-40, 2005.

H. Xiao, Characterization of Matrices Generating Orthogonal Multi-wavelets, 2009 International Joint Conference on Computational Sciences and Optimization, p.76700, 2009.

F. ;. Harfleur and . Total-raffinage-chimie, TRTG, p.76700

F. Harfleur, . Uppa, . Cnrs, and . Iprem, Institut des Sciences Analytiques et de Physico-chimie pour l'Environnement et les Materiaux, UMR5254, He?ioparc, vol.407, p.752

E. Jakobs, Telefon, Email oder Fax?, Schreiben fürs Netz, pp.26-40, 2005.

A. Jonathan, C. Putman, and ?. , United States Re?i Moulian ? International Joint Laboratory?iC2MC: Complex Matrices Molecular Characterization, vol.80223, p.76700

F. ;. Harfleur and . Total-raffinage-chimie, TRTG, p.76700

F. Harfleur, . Uppa, . Cnrs, and . Iprem, Institut des Sciences Analytiques et de Physico-chimie pour l'Environnement et les Materiaux, UMR5254, He?ioparc, p.64053

F. Donald and ?. Smith, Schrieffer, Prof. John Robert, (born 31 May 1931), University Professor, Florida State University, 1992 (Chief Scientist, National High Magnetic Field Laboratory, 1992?2004); University Eminent Scholar Professor, State of Florida University System, 1995, 2007.

C. R. Weisbrod and ?. , Schrieffer, Prof. John Robert, (born 31 May 1931), University Professor, Florida State University, 1992 (Chief Scientist, National High Magnetic Field Laboratory, 1992?2004); University Eminent Scholar Professor, State of Florida University System, 1995, 2007.

M. L. Chaco?-patinõ, Schrieffer, Prof. John Robert, (born 31 May 1931), University Professor, Florida State University, 1992 (Chief Scientist, National High Magnetic Field Laboratory, 1992?2004); University Eminent Scholar Professor, State of Florida University System, 1995, 2007.

Y. E. Corilo and ?. , Schrieffer, Prof. John Robert, (born 31 May 1931), University Professor, Florida State University, 1992 (Chief Scientist, National High Magnetic Field Laboratory, 1992?2004); University Eminent Scholar Professor, State of Florida University System, 1995, 2007.

L. E. Rumancik and ?. , United States Caroline Barrere-Mangote ? International Joint Laboratory?iC2MC: Complex Matrices Molecular Characterization, TRTG, p.76700, 32304.

P. Ryan and ?. Rodgers, Schrieffer, Prof. John Robert, (born 31 May 1931), University Professor, Florida State University, 1992 (Chief Scientist, National High Magnetic Field Laboratory, 1992?2004); University Eminent Scholar Professor, State of Florida University System, 1995, International Joint Laboratory?iC2MC: Complex Matrices Molecular Characterization, p.76700, 2007.

F. Harfleur, . Uppa, . Cnrs, and . Iprem, Institut des Sciences Analytiques et de Physico-chimie pour l'Environnement et les Materiaux, UMR5254, He?ioparc, p.64053

P. Giusti and ?. , International Joint Laboratory?iC2MC: Complex Matrices Molecular Characterization, p.76700

F. ;. Harfleur and . Total-raffinage-chimie, TRTG, p.76700

F. Harfleur,

, Complete contact information is

, Energy & Fuels pubs.acs.org/EF Article, vol.34, pp.10915-10925, 2020.

?. References, Voltage References, Voltage References, 2009.

K. Akbarzadeh, A. Hammami, A. Kharrat, D. Zhang, S. Allenson et al., Asphaltenes, Heavy Oils, and Petroleomics, Oilf. Rev, vol.19, issue.2, pp.22-43, 2007.

M. L. Chaco?-patinõ, S. M. Rowland, and R. P. Rodgers, Energy Fuels, vol.32, issue.1, pp.314-328, 2018.

A. A. Herod, Limitations of mass spectrometric methods for the characterization of polydisperse materials, Rapid Communications in Mass Spectrometry, vol.24, issue.17, pp.2507-2519, 2010.

A. A. Herod, K. D. Bartle, T. J. Morgan, and R. Kandiyoti, Analytical Methods for Characterizing High-Mass Complex Polydisperse Hydrocarbon Mixtures: An Overview, Chemical Reviews, vol.112, issue.7, pp.3892-3923, 2012.

A. M. Mckenna, A. G. Marshall, and R. P. Rodgers, Heavy Petroleum Composition. 4. Asphaltene Compositional Space, Energy & Fuels, vol.27, issue.3, pp.1257-1267, 2013.

J. M. Purcell, I. Merdrignac, R. P. Rodgers, A. G. Marshall, T. Gauthier et al., Stepwise Structural Characterization of Asphaltenes during Deep Hydroconversion Processes Determined by Atmospheric Pressure Photoionization (APPI) Fourier Transform Ion Cyclotron Resonance (FT-ICR) Mass Spectrometry?, Energy & Fuels, vol.24, issue.4, pp.2257-2265, 2010.

T. Fan and J. S. Buckley, Rapid and Accurate SARA Analysis of Medium Gravity Crude Oils, Energy & Fuels, vol.16, issue.6, pp.1571-1575, 2002.

J. T. Miller, R. B. Fisher, P. Thiyagarajan, R. E. Winans, and J. E. Hunt, Subfractionation and Characterization of Mayan Asphaltene, Energy & Fuels, vol.12, issue.6, pp.1290-1298, 1998.

E. Rogel, M. Roye, J. Vien, and T. Miao, Characterization of Asphaltene Fractions: Distribution, Chemical Characteristics, and Solubility Behavior, Energy & Fuels, vol.29, issue.4, pp.2143-2152, 2015.

E. Buenrostro-gonzalez, H. Groenzin, C. Lira-galeana, and O. C. Mullins, The Overriding Chemical Principles that Define Asphaltenes, Energy & Fuels, vol.15, issue.4, pp.972-978, 2001.

B. E. Hansen, O. Malmros, N. R. Turner, E. H. Stenby, and S. Andersen, Proceedings of Light Metals, pp.559-564, 2001.

M. J. Lazaro, C. A. Islas, A. A. Herod, and R. Kandiyoti, Calibration of Size Exclusion Chromatography in 1-Methyl-2-pyrrolidinone for Coal-Derived Materials Using Standards and Mass Spectrometry, Energy & Fuels, vol.13, issue.6, pp.1212-1222, 1999.

C. Berrueco, S. Venditti, T. J. Morgan, P. A?lvarez, M. Millan et al., Calibration of Size-Exclusion Chromatography Columns with 1-Methyl-2-pyrrolidinone (NMP)/Chloroform Mixtures as Eluent: Applications to Petroleum-Derived Samples, Energy & Fuels, vol.22, issue.5, pp.3265-3274, 2008.

J. C. Putman, S. Gutiérrez-sama, C. Barrère-mangote, R. P. Rodgers, R. Lobinski et al., Analysis of Petroleum Products by Gel Permeation Chromatography Coupled Online with Inductively Coupled Plasma Mass Spectrometry and Offline with Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Energy & Fuels, vol.32, issue.12, pp.12198-12204, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01917154

P. Qiao, D. Harbottle, P. Tchoukov, J. Masliyah, J. Sjoblom et al., Fractionation of Asphaltenes in Understanding Their Role in Petroleum Emulsion Stability and Fouling, Energy & Fuels, vol.31, issue.4, pp.3330-3337, 2017.

M. Orea, M. A. Ranaudo, P. Lugo, and L. López, Retention of Alkane Compounds on Asphaltenes. Insights About the Nature of Asphaltene?Alkane Interactions, Energy & Fuels, vol.30, issue.10, pp.8098-8113, 2016.

T. Ghislain, L. Molnárné-guricza, and W. Schrader, Characterization of crude oil asphaltenes by coupling size-exclusion chromatography directly to an ultrahigh-resolution mass spectrometer, Rapid Communications in Mass Spectrometry, vol.31, issue.6, pp.495-502, 2017.

S. K. Panda, N. A. Alawani, A. R. Lajami, T. A. Al-qunaysi, and H. Muller, Characterization of aromatic hydrocarbons and sulfur heterocycles in Saudi Arabian heavy crude oil by gel permeation chromatography and ultrahigh resolution mass spectrometry, Fuel, vol.235, pp.1420-1426, 2019.

N. A. Alawani, S. K. Panda, A. R. Lajami, T. A. Al-qunaysi, and H. Muller, Characterization of Crude Oils through Alkyl Chain-Based Separation by Gel Permeation Chromatography and Mass Spectrometry, Energy & Fuels, vol.34, issue.5, pp.5414-5425, 2020.

H. Xu, G. Que, D. Yu, and J. R. Lu, Characterization of Petroporphyrins Using Ultraviolet?Visible Spectroscopy and Laser Desorption Ionization Time-of-Flight Mass Spectrometry, Energy & Fuels, vol.19, issue.2, pp.517-524, 2005.

L. Lo?ez, S. Lo-mo?aco, and M. Richardson, Org. Geochem, vol.29, pp.613-629, 1998.

G. Gascon, V. Vargas, L. Feo, O. Castellano, J. Castillo et al., Size Distributions of Sulfur, Vanadium, and Nickel Compounds in Crude Oils, Residues, and Their Saturate, Aromatic, Resin, and Asphaltene Fractions Determined by Gel Permeation Chromatography Inductively Coupled Plasma High-Resolution Mass Spectrometry, Energy & Fuels, vol.31, issue.8, pp.7783-7788, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01755104

A. Desprez, B. Bouyssiere, C. Arnaudguilhem, G. Krier, L. Vernex-loset et al., Study of the Size Distribution of Sulfur, Vanadium, and Nickel Compounds in Four Crude Oils and Their Distillation Cuts by Gel Permeation Chromatography Inductively Coupled Plasma High-Resolution Mass Spectrometry, Energy & Fuels, vol.28, issue.6, pp.3730-3737, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01518900

S. Gutierrez-sama, A. Desprez, G. Krier, C. Lienemann, J. J. Barbier et al., Study of the Aggregation of Metal Complexes with Asphaltenes Using Gel Permeation Chromatography Inductively Coupled Plasma High-Resolution Mass Spectrometry, Energy & Fuels, vol.30, issue.9, pp.6907-6912, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01498745

Q. Cui, K. Nakabayashi, X. Ma, J. Miyawaki, A. Al-mutairi et al., Energy Fuels, vol.31, issue.7, pp.1065-1071, 2017.

S. Sato, T. Takanohashi, and R. Tanaka, Molecular Weight Calibration of Asphaltenes Using Gel Permeation Chromatography/Mass Spectrometry, Energy & Fuels, vol.19, issue.5, pp.1991-1994, 2005.

L. Prokai and W. J. Simonsick, Electrospray ionization mass spectrometry coupled with size-exclusion chromatography, Rapid Communications in Mass Spectrometry, vol.7, issue.9, pp.853-856, 1993.

G. H. Lathe and C. R. Ruthven, The separation of substances and estimation of their relative molecular sizes by the use of columns of starch in water, Biochemical Journal, vol.62, issue.4, pp.665-674, 1956.

S. M. Rowland, W. K. Robbins, Y. E. Corilo, A. G. Marshall, and R. P. Rodgers, Solid-Phase Extraction Fractionation To Extend the Characterization of Naphthenic Acids in Crude Oil by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Energy & Fuels, vol.28, issue.8, pp.5043-5048, 2014.

N. Itoh, Y. Aoyagi, and T. Yarita, Optimization of the dopant for the trace determination of polycyclic aromatic hydrocarbons by liquid chromatography/dopant-assisted atmospheric-pressure photoionization/mass spectrometry, Journal of Chromatography A, vol.1131, issue.1-2, pp.285-288, 2006.

D. B. Robb, T. R. Covey, and A. P. Bruins, Atmospheric Pressure Photoionization: An Ionization Method for Liquid Chromatography?Mass Spectrometry, Analytical Chemistry, vol.72, issue.15, pp.3653-3659, 2000.

G. Andreatta, N. Bostrom, and O. C. Mullins, High-QUltrasonic Determination of the Critical Nanoaggregate Concentration of Asphaltenes and the Critical Micelle Concentration of Standard Surfactants, Langmuir, vol.21, issue.7, pp.2728-2736, 2005.

J. C. Putman, R. Moulian, C. Barrère-mangote, R. P. Rodgers, B. Bouyssiere et al., Probing Aggregation Tendencies in Asphaltenes by Gel Permeation Chromatography. Part 1: Online Inductively Coupled Plasma Mass Spectrometry and Offline Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Energy & Fuels, vol.34, issue.7, pp.8308-8315, 2020.
URL : https://hal.archives-ouvertes.fr/hal-03006658

D. R. Smith, D. B. Robb, and M. W. Blades, Comparison of dopants for charge exchange ionization of nonpolar polycyclic aromatic hydrocarbons with reversed-phase LC-APPI-MS, Journal of the American Society for Mass Spectrometry, vol.20, issue.1, pp.73-79, 2009.

J. C. Putman, R. Moulian, D. F. Smith, C. R. Weisbrod, M. L. Chacón-patiño et al., Probing Aggregation Tendencies in Asphaltenes by Gel Permeation Chromatography. Part 2: Online Detection by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry and Inductively Coupled Plasma Mass Spectrometry, Energy & Fuels, vol.34, issue.9, pp.10915-10925, 2020.
URL : https://hal.archives-ouvertes.fr/hal-03006658

S. Lababidi and W. Schrader, Online normal-phase high-performance liquid chromatography/Fourier transform ion cyclotron resonance mass spectrometry: Effects of different ionization methods on the characterization of highly complex crude oil mixtures, Rapid Communications in Mass Spectrometry, vol.28, issue.12, pp.1345-1352, 2014.

L. Molna?ne?guricza and W. Schrader, , vol.215, pp.631-637, 2018.

P. Giusti, Y. Nuevo-ordóñez, C. Philippe-lienemann, D. Schaumlöffel, B. Bouyssiere et al., ?Flow-injection?ICP collision cell MS determination of molybdenum, nickel and vanadium in petroleum samples using a modified total consumption micronebulizer, J. Anal. At. Spectrom., vol.22, issue.1, pp.88-92, 2007.

G. Caumette, C. Lienemann, I. Merdrignac, H. Paucot, B. Bouyssiere et al., Sensitivity improvement in ICP MS analysis of fuels and light petroleum matrices using a microflow nebulizer and heated spray chamber sample introduction, Talanta, vol.80, issue.2, pp.1039-1043, 2009.
URL : https://hal.archives-ouvertes.fr/hal-01560746

C. L. Hendrickson, J. P. Quinn, N. K. Kaiser, D. F. Smith, G. T. Blakney et al., 21 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer: A National Resource for Ultrahigh Resolution Mass Analysis, Journal of The American Society for Mass Spectrometry, vol.26, issue.9, pp.1626-1632, 2015.

D. F. Smith, D. C. Podgorski, R. P. Rodgers, G. T. Blakney, and C. L. Hendrickson, 21 Tesla FT-ICR Mass Spectrometer for Ultrahigh-Resolution Analysis of Complex Organic Mixtures, Analytical Chemistry, vol.90, issue.3, pp.2041-2047, 2018.

G. T. Blakney, C. L. Hendrickson, and A. G. Marshall, Predator data station: A fast data acquisition system for advanced FT-ICR MS experiments, International Journal of Mass Spectrometry, vol.306, issue.2-3, pp.246-252, 2011.

F. Xian, C. L. Hendrickson, G. T. Blakney, S. C. Beu, and A. G. Marshall, Automated Broadband Phase Correction of Fourier Transform Ion Cyclotron Resonance Mass Spectra, Analytical Chemistry, vol.82, issue.21, pp.8807-8812, 2010.

G. T. Blakney, C. L. Hendrickson, and A. G. Marshall, Predator data station: A fast data acquisition system for advanced FT-ICR MS experiments, International Journal of Mass Spectrometry, vol.306, issue.2-3, pp.246-252, 2011.

Y. E. Corilo, . Petroorg, and . Software, Test Method for Determination of Asphaltenes (Heptane Insolubles) in Crude Petroleum and Petroleum Products

M. L. Chaco?-patinõ, S. J. Vesga-martínez, C. Blanco-tirado, J. A. Orrego-ruiz, A. Go?ez-escudero et al., Energy Fuels, vol.30, issue.6, pp.4550-4561, 2016.

M. Derakhshesh, A. Bergmann, and M. R. Gray, Occlusion of Polyaromatic Compounds in Asphaltene Precipitates Suggests Porous Nanoaggregates, Energy & Fuels, vol.27, issue.4, pp.1748-1751, 2012.

O. P. Strausz, M. Torres, E. M. Lown, I. Safarik, and J. Murgich, Equipartitioning of Precipitant Solubles between the Solution Phase and Precipitated Asphaltene in the Precipitation of Asphaltene, Energy & Fuels, vol.20, issue.5, pp.2013-2021, 2006.

P. Giusti, B. Bouyssière, H. Carrier, and C. Afonso, 18th International Conference on Petroleum Phase Behavior and Fouling, Energy & Fuels, vol.32, issue.3, pp.2641-2641, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01781968

S. Silva, H. Sodero, A. C. Korb, J. P. Alfarra, A. Giusti et al., , vol.188, pp.374-381, 2017.

S. Silva, H. Sodero, A. C. Korb, J. P. Alfarra, A. Giusti et al., , vol.188, pp.374-381, 2017.

S. Silva, H. Alfarra, A. Vallverdu, G. Be?ue, D. Bouyssiere et al., Baraille, I. Pet. Sci, vol.2020, issue.3, pp.797-810

, Energy & Fuels pubs.acs.org/EF Article, vol.34, pp.10915-10925, 2020.

C. S. Hsu, V. V. Lobodin, R. P. Rodgers, A. M. Mckenna, and A. G. Marshall, Compositional Boundaries for Fossil Hydrocarbons, Energy & Fuels, vol.25, issue.5, pp.2174-2178, 2011.

, Energy & Fuels pubs.acs.org/EF Article, vol.34, pp.10915-10925, 2020.