The vacuum ultraviolet spectrum of stannane

J. Fernandez , Gaetane Lespes (1) , Alain Dargelos

1 IPREM - Institut pluridisciplinaire de recherche sur l'environnement et les matériaux

The vacuum UV spectrum of SnH4 has been recorded up to 110nm (12.26 eV). This spectrum has been interpreted by ab initio calculations (SCF + CI), using a relativistic pseudopotential to describe the core electrons of the tin atom. The spectrum consists of a broad band composed of three maxima (at 8.73, 9.53 and 11.33 eV). The transition below 9.50 eV have been attributed to transitions to diffuse Rydberg states (6s and 6p). The other bands are due essentially to valence transitions. © 1986.

Domaines: Chimie analytique; Sciences de l'environnement

J. Fernandez, Gaetane Lespes, Alain Dargelos. The vacuum ultraviolet spectrum of stannane. Chemical Physics, 1986, 103 (1), pp.85-91. ⟨10.1016/0301-0104(86)85104-7⟩. ⟨hal-01624885⟩