Quasi-thermoneutral P → B interactions within di- and tri-phosphine boranes

Sébastien Bontemps (1) , G. Bouhadir (1) , P.W. Dyer (2) , Karinne Miqueu (3) , D. Bourissou (1)

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée
2 Department of Chemistry [Durham, UK]
3 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

Spectroscopic, structural, and theoretical evidence is provided for both open (no intramolecular P → B interaction) and closed (with intramolecular P → B interaction) forms of the di- and tri-phosphine boranes [o-(iPr 2P)C6H4]2BPh (2) and [o-(iPr 2P)C6H4]3B (3). © 2007 American Chemical Society.

Domains: Catalysis; Coordination chemistry; Organic chemistry; Polymers; Theoretical and/or physical chemistry

Sébastien Bontemps, G. Bouhadir, P.W. Dyer, Karinne Miqueu, D. Bourissou. Quasi-thermoneutral P → B interactions within di- and tri-phosphine boranes. Inorganic Chemistry, 2007, 46 (13), pp.5149-5151. ⟨10.1021/ic7006556⟩. ⟨hal-01613261⟩