In situ generated, polymer-supported organotin hydrides as clean reducing agents

G. Dumartin , M. Pourcel , B. Delmond , Olivier François Xavier Donard (1) , M. Pereyre

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

Polymer-supported organotin hydrides were generated in-situ from polymer-supported organotin halides and NaBH4. Their reducing ability was monitored by reaction with 1-bromoadamantane. The residual tin pollution was estimated by ICP-MS.

Domaines: Chimie analytique

G. Dumartin, M. Pourcel, B. Delmond, Olivier François Xavier Donard, M. Pereyre. In situ generated, polymer-supported organotin hydrides as clean reducing agents. Tetrahedron Letters, 1998, 39 (26), pp.4663-4666. ⟨10.1016/S0040-4039(98)00873-9⟩. ⟨hal-01590103⟩