Flash vacuum thermolysis of 1-azabicyclo[1.1.0]butanes. Photoelectron spectrum of 3-phenyl-2-azabuta-1,3-diene

R. Bartnik , Patrick Baylère (1) , Anna Chrostowska (1) , A. Galindo , S. Leśniak , G. Pfister-Guillouzo

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux

The reaction behaviour of 1-azabicyclo[1.1.0]butanes under flash vacuum thermolysis (FVT) conditions was studied. It has been found that the thermal rearrangement of title compounds produces unstable 2-aza-1,3-dienes. The formation of these products was established by reduction, by Diels-Alder reactions and by UV photoelectron spectroscopy. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

Mots clés: flash pyrolysis; Ionisation potentials; Photoelectron Spectroscopy; Quantum mechanical calculations; small ring systems

Domaines: Chimie inorganique; Chimie organique

R. Bartnik, Patrick Baylère, Anna Chrostowska, A. Galindo, S. Leśniak, et al.. Flash vacuum thermolysis of 1-azabicyclo[1.1.0]butanes. Photoelectron spectrum of 3-phenyl-2-azabuta-1,3-diene. European Journal of Organic Chemistry, 2003, 13, pp.2475--2479. ⟨hal-01566352⟩