Lithium insertion in copper, indium, tin thiospinels characterized by 119Sn Mossbauer spectroscopy and Rietveld analysis

Rémi Dedryvère (1) , J. Olivier-Fourcade (2) , J.C. Jumas (2) , S. Denis (3) , C. Perez Vicente

1 IPREM - Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux
2 ICGM ICMMM - Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier
3 LRCS - Laboratoire réactivité et chimie des solides - UMR CNRS 7314

Chemical lithium insertion via n-butyllithium was carried out on a family of spinel phases of the Cu2S-In2S3-SnS2 system, of general formula Cu0.5+(α)In2.5-3(α)Sn2(α)S4, 0 ≤ α ≤ 0.5. Structural analyses were performed by X-ray and neutron powder diffraction (Rietveld method) and 119Sn Mossbauer spectroscopy. Two mechanisms of lithium insertion occur at the same time. The first is characterized by the reduction of Sn(IV) into Sn(II) and a spinel to rocksalt transformation. The second leads to the total reduction of tin cations into Sn0 and the formation of metallic bonds in an amorphous phase. The relative amounts of indium and tin are discussed with respect to the crystallinity of the rocksalt phase. An electrochemical study was carried out to evaluate the cycling behavior of these compounds, and their possible use as anode material in lithium ion cells.

Domaines: Matériaux

Rémi Dedryvère, J. Olivier-Fourcade, J.C. Jumas, S. Denis, C. Perez Vicente. Lithium insertion in copper, indium, tin thiospinels characterized by 119Sn Mossbauer spectroscopy and Rietveld analysis. Chemistry of Materials, 2000, 12 (5), pp.1439-1445. ⟨10.1021/cm991190j⟩. ⟨hal-01560714⟩